trans-Tris(4-bromophenyl)dichloridoantimony(V)
نویسندگان
چکیده
The Sb(V) atom in the title compound, [SbCl2(C6H4Br)3], has an almost regular trigonal-bipyramidal geometry with the equatorial plane made up of three C atoms of the bromo-phenyl groups and the axial positions occupied by two Cl(-) ions in a trans configuration. In the crystal, C-H⋯Br hydrogen bonds link the mol-ecules into zigzag chains along the b-axis direction. Pairs of C-H⋯Cl hydrogen bonds further link mol-ecules into cyclic dimers with R2(2)(10) ring motifs, generating a three-dimensional network.
منابع مشابه
4-(Dimethylamino)pyridinium dibromido(4-bromophenyl)dimethylstannate(IV)
The anion in the title compound, (C(7)H(11)N(2))[SnBr(2)(CH(3))(2)(C(6)H(4)Br)], is five-coordinate within a distorted trans-C(3)SnBr(2) trigonal-bipyramidal geometry. The cation and anion are linked by an N-H⋯Br hydrogen bond.
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